I would like to suggest two things:
1) first tanks are always disappointing - it takes time to learn how to get the most out your vehicle. My first Prius tank was 39 MPG and I was about ready to turn it back in.
2) nothing like a nice long trip, ~ 1 hr at highway speeds - this will get all of the lubricants up to temperature, coolants working, batteries charged and generally "blow out the cob-webs." Don't worry about the mileage, just enjoy the car.
If the 12VDC battery were kaput, your car wouldn't start. If the traction battery were kaput, your car wouldn't start and all sorts of alarms would go off. Sad to say, there are no good "metrics" to read out the state of your batteries while they are in the car. But folks are investigating this all of the time.
Although not exactly the same, you are free to look over the Prius FAQ for suggestions:
http://greenhybrid.com/discuss/showthread.php?t=6645
BTW, I don't use P&G.
GOOD LUCK!
Bob Wilson