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I wonder why the EPA has the city listed at a higher rate than highway, when all of your real life numbers seem to indicate the opposite... if the EPA numbers were the other way around (40 HW, 38 City), I would qualify for no sales tax on the purchase...
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The problem is that the EPA City test has too few stops, that are too far apart to accurately represent most cities. Also, those tests are flats. Throw in stops on hills (incline or decline) like you see in many cities, you can kiss any chance of conserving your momentum (
the key to good mileage IMO) goodbye. While the hybrid pack helps some -- reclaiming some energy that would otherwise be wasted braking, constanty stopping and going is, and always will be less efficient than steady-state driving, from a physics perspective. Also, in many cases on steep hills, braking will be required beyond the capacity of the regenerative braking anyway -- on a highway with hills though, you can drive with load and regain momentum going down -- a more efficient method of storing energy than a chemical battery pack.
As far as acceleration, the key will be to accelerate where possible at the engine's most efficient RPM range -- it will take the same amount of energy to accelerate the vehicle to a certain speed whether it is done slowly or quickly, so the best bet is to accelerate with the engine running at its most efficient RPM until you reach your desired speed, which is around 2000 on my vehicle, I don't know what it is on the Camry however.
Also, going out of your way to use all-elecrtic mode may not be the best bet in all situations -- while no gas is burned at the time, it will need to be paid back later with charging on the engine. If you know there will be a big hill or something where you can regenerate energy, then I'd reccomend using the battery more heavily, but if not, you're liekly better off simply letting the engine run if the car wants it to.